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• W2401797946 startingPage "838" @default.
• W2401797946 abstract "The self-assembly behavior of sphere-forming R5C30R5 triblock copolymers within a planar slit is studied by performing dissipative particle dynamics simulations. A sequence of novel structures which are not observed in bulk are formed within slits, including wetting layers, island-like structure, parallel cylinders, perpendicular cylinders and cross-cylindrical structures. Perpendicular cylinders are always formed before the increase in the layers of parallel cylinders. A phase diagram of the assembled structures with respective to the slit property and height is thus presented. The rod length is found to have a significant impact on the rod alignment, and a disordered-ordered transition of rod orientation occurs with an increase in the length of rod blocks. Some special structures, such as parallel half-cylinders and arrowhead-shaped morphology, are observed when the rod length increases to a certain extent. Our results show that the property and height of the slit and rod length all influence the self-assembly of rod-coil-rod triblock copolymers." @default.
• W2401797946 created "2016-06-24" @default.
• W2401797946 creator A5036733765 @default.
• W2401797946 creator A5089435863 @default.
• W2401797946 date "2016-05-21" @default.
• W2401797946 modified "2023-10-10" @default.
• W2401797946 title "Self-assembly behavior of rod-coil-rod triblock copolymers within a planar slit" @default.
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• W2401797946 doi "https://doi.org/10.1007/s10118-016-1803-7" @default.
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