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• W2404005384 abstract "The oxidation treatment of needle cokes with 70 wt% of nitric acid and sodium chlorate (NaClO3) was attempted to achieve an electrochemically active material with a large capacitance. The structure of needle cokes was changed to graphite oxide after oxidation treatment of needle cokes with acidic solution having the composition ratio, NaClO3/needle cokes, of 7.5, and the inter-layer distance of the oxidized needle cokes was extended to 6.9 Å with increasing oxygen content. On the other hand, the electrochemical performance of oxidized needle cokes as a polarized electrode for an Electric Double Layer Capacitor (EDLC) was examined with an electrolyte of 1.2 M TEABF4 (tetraethylammonium tetrafluoroborate) and TEMABF4 (triethylmethylammonium tetrafluoroborate) in acetonitrile. The capacitor cell using 1.2 M TEMABF4/acetonitrile has exhibited smaller electric resistance of 0.05 Ω, and larger capacitance per weight and volume of 32.0 F/g and 25.5 F/mL at the twoelectrode system in the potential range 0∼2.5 V than that of the capacitor cell using TEABF4. The observed electrochemical performance was discussed with the correlation between the inter-layer distance in graphite oxide structure and the anionic size of electrolyte." @default.
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• W2404005384 date "2007-01-01" @default.
• W2404005384 modified "2023-09-23" @default.
• W2404005384 title "Preparation of Graphite Oxide and its Electrochemical Double Layer Capacitor's Performances using Non-Aqueous Electrolyte (TEABF 4 & TEMABF 4 )" @default.
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