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- W2404278319 abstract "Analyses of the chief volatile constituents of the defensive secretions of three oplionids were carried out. Leiobunum nigripalpi produces three closely related C7 com- pounds: E-4-methyl-4-hexen-3-one(I), 4-methylhexan-3-one(II), and 4-methylhexan-3-ol(III), along with E4-methyl-4-hepten- 3-one(IV), E,E-2,4-dimethylhexa-2,4-dienal(IX), and a minor, unidentified component. L. Ieiopenis secretion contains E-4- methyl4-hepten-3-one(IV), 4-methylheptan-3-one(V), E,E-2,4- dimethylhexa-2,4-dien-1-ol(VII), and E,E-2,4-dimethylhepta- 2,4-dien-1-ol(VIII). L. calcar yields chiefly E4,6-dimethyl-6- octen-3-one(VI) and E,E-2,4-dimethylhexa-2,4-dien-l-ol(VII). Six of these compounds are new natural products. The structures of these compounds, which can be regarded either as polyke- tide-derived or as modified isoprenoids, raise interesting bio- synthetic questions." @default.
- W2404278319 created "2016-06-24" @default.
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- W2404278319 date "2016-01-01" @default.
- W2404278319 modified "2023-09-27" @default.
- W2404278319 title "Characterization and synthesis of volatile compounds from the defensive secretions of some daddy longlegs (Arachnida: Opiliones: Leiobunum spp.)* (arthropods/integumental glands/acyclic alcohols, aldehydes, and ketones)" @default.
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