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- W2405254013 abstract "Abstract Hexafluoropropene trimers were reacted with C 6 F 5 Si(CH 3 ) 3 to provide not only pentafluorophenyl but also perfluorophenylene derivatives [F(C 6 F 4 ) n C 9 F 17 ; n =2–9] by successive pentafluorophenylation of perfluoroaryl rings. Their structures, including rotational isomers, were determined by MS, 19 F and 13 C–{ 19 F} NMR spectroscopy, and/or X‐ray crystallography, and were further confirmed by B3LYP‐GIAO calculation of NMR shieldings. Formation of a pair of gear‐meshed rotamers with clockwise and counterclockwise conformations was identified by NMR measurements for the structures having geminal (CF 3 ) 2 CF groups at the C=C bond. That the predominantly formed counterclockwise rotamer was gradually converted to the clockwise rotamer over 50 days at room temperature through a synchronized movement of gears was also confirmed by NMR measurements. A comparison between the X‐ray structure and B3LYP calculations showed some structural differences that arise from the crystal packing." @default.
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- W2405254013 date "2016-06-13" @default.
- W2405254013 modified "2023-10-09" @default.
- W2405254013 title "Reactions of Highly Branched Perfluoroolefins with (Pentafluorophenyl)trimethylsilane: Characterization of the Unique Structural Properties of Perfluorinated Super-Congested Systems" @default.
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- W2405254013 doi "https://doi.org/10.1002/ajoc.201600167" @default.
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