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• W2405798966 abstract "Ultrafast pump-probe spectroscopy within the X-ray regime is now possible owing to the development of X-ray Free Electrons Lasers (X-FELs) and is opening new opportunities for the direct probing of femtosecond evolution of the nuclei, the electronic and spin degrees of freedom. In this contribution we use wavepacket dynamics of the photoexcited decay of a new Fe(<sc>ii</sc>) complex, [Fe(bmip)₂]²⁺ (bmip = 2,6-bis(3-methyl-imidazole-1-ylidine)pyridine), to simulate the experimental observables associated with femtosecond Fe K-edge X-ray Absorption Near-Edge Structure (XANES) and X-ray emission (XES) spectroscopy. We show how the evolution of the nuclear wavepacket is translated into the spectroscopic signal and the sensitivity of these approaches for following excited state dynamics." @default.
• W2405798966 created "2016-06-24" @default.
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• W2405798966 date "2016-01-01" @default.
• W2405798966 modified "2023-10-16" @default.
• W2405798966 title "Probing spin–vibronic dynamics using femtosecond X-ray spectroscopy" @default.
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• W2405798966 doi "https://doi.org/10.1039/c6fd00070c" @default.
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• W2405798966 hasPublicationYear "2016" @default.
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