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- W2406199000 abstract "Chloro- and bromodeoxycelluloses with high degrees of halogen substitution were treated with inorganic halides, thiocyanate and cyanide in N, N-dimethylacetamide or N, N-dimethylformamide. The reaction systems were homogeneous in most cases. The products were hydrolyzed and the resulting saccharides were analyzed by gas chromatography and gas chromatography-mass spectrometry as their trifluoroacetyl derivatives. The reactivity of halide ions in nucleophilic substitution increased in the order I-<Br-<Cl-, which agrees with the order of nucleophilicity of unsolvated halide ions in aprotic organic solvents. The reaction of halodeoxycelluloses with KSCN yielded thiocyanatodeoxycelluloses with more than 90% conversion at 150°C in 2h. The reaction of bromodeoxycellulose with KCN at 100°C for 2h did not give cyanodeoxycellulose, and most of the 6-bromo-6-deoxyglucose units were converted into 3, 6-anhydroglucose units." @default.
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- W2406199000 date "1992-01-01" @default.
- W2406199000 modified "2023-09-23" @default.
- W2406199000 title "Reactions of halodeoxycelluloses with inorganic nucleophiles in aprotic amide solvents." @default.
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- W2406199000 doi "https://doi.org/10.2115/fiber.48.11_602" @default.
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