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- W2406860839 abstract "The binding features of a sulfonato-calix[4]arene with pyridinium-based gemini guests have been investigated in water at physiological condition by NMR spectroscopy. Results provided converging evidence showing that guests having different size, shape and flexibility formed water-soluble homodimeric supramolecular capsules. The remarkably large encapsulation efficiency of the anionic calixarene host towards these bis(pyridinium) gemini guests results from the favourable combination of electrostatic and hydrophobic interactions. The introduction of short and rigid spacers between the two positively charged heads of the guest improves the efficiency of the capsule formation. The insertion of a substituent into the pyridinium ring of the guest dramatically affects both the association constants and the binding modes." @default.
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- W2406860839 date "2016-01-20" @default.
- W2406860839 modified "2023-09-30" @default.
- W2406860839 title "Cationic gemini guests promote the efficient self-assembly of capsular entities in water at neutral pH" @default.
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- W2406860839 doi "https://doi.org/10.1080/10610278.2015.1131986" @default.
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