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- W2406877987 abstract "Understanding the fundamental relationship between the size and the structure of electrode materials is essential to design catalysts and enhance their activity. Therefore, spherical gold nanoparticles (GNSs) with a mean diameter from 4 to 15 nm were synthesized. UV/Vis spectroscopy, transmission electron microscopy, and under-potential deposition of lead (UPDPb) were used to determine the morphology, size, and surface crystallographic structure of the GNSs. The UPDPb revealed that their crystallographic facets are affected by their size and the growth process. The catalytic properties of these GNSs toward glucose electrooxidation were studied by cyclic voltammetry, taking into account the scan rate and temperature effects. The results clearly show the size-dependent electrocatalytic activity for glucose oxidation reactions that are controlled by diffusion. Small GNSs with an average size of 4.2 nm exhibited high catalytic activity. This drastic increase in activity results from the high specific area and reactivity of the surface electrons induced by their small size. The reaction mechanism was investigated by in situ Fourier transform infrared reflectance spectroscopy. Gluconolactone and gluconate were identified as the intermediate and the final reaction product, respectively, of the glucose electrooxidation." @default.
- W2406877987 created "2016-06-24" @default.
- W2406877987 creator A5009406696 @default.
- W2406877987 creator A5029724895 @default.
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- W2406877987 date "2016-03-11" @default.
- W2406877987 modified "2023-10-16" @default.
- W2406877987 title "Size-Dependent Electrocatalytic Activity of Free Gold Nanoparticles for the Glucose Oxidation Reaction" @default.
- W2406877987 cites W145224721 @default.
- W2406877987 cites W1966430130 @default.
- W2406877987 cites W1968306116 @default.
- W2406877987 cites W1969645755 @default.
- W2406877987 cites W1970092748 @default.
- W2406877987 cites W1972448498 @default.
- W2406877987 cites W1975916882 @default.
- W2406877987 cites W1982832557 @default.
- W2406877987 cites W1985489625 @default.
- W2406877987 cites W1987197010 @default.
- W2406877987 cites W1992790616 @default.
- W2406877987 cites W1993333710 @default.
- W2406877987 cites W1993850257 @default.
- W2406877987 cites W1995254004 @default.
- W2406877987 cites W1996680665 @default.
- W2406877987 cites W1997594509 @default.
- W2406877987 cites W1998089190 @default.
- W2406877987 cites W2000993740 @default.
- W2406877987 cites W2005355202 @default.
- W2406877987 cites W2006925023 @default.
- W2406877987 cites W2007618803 @default.
- W2406877987 cites W2008030497 @default.
- W2406877987 cites W2013612526 @default.
- W2406877987 cites W2014161704 @default.
- W2406877987 cites W2018533798 @default.
- W2406877987 cites W2018725655 @default.
- W2406877987 cites W2025295644 @default.
- W2406877987 cites W2025709161 @default.
- W2406877987 cites W2026258028 @default.
- W2406877987 cites W2030826093 @default.
- W2406877987 cites W2033412312 @default.
- W2406877987 cites W2034720347 @default.
- W2406877987 cites W2034883225 @default.
- W2406877987 cites W2035348092 @default.
- W2406877987 cites W2036285102 @default.
- W2406877987 cites W2043494536 @default.
- W2406877987 cites W2050061183 @default.
- W2406877987 cites W2051255154 @default.
- W2406877987 cites W2054950562 @default.
- W2406877987 cites W2058895121 @default.
- W2406877987 cites W2060708522 @default.
- W2406877987 cites W2061239482 @default.
- W2406877987 cites W2062921532 @default.
- W2406877987 cites W2067333661 @default.
- W2406877987 cites W2068509382 @default.
- W2406877987 cites W2069015247 @default.
- W2406877987 cites W2070247802 @default.
- W2406877987 cites W2072734897 @default.
- W2406877987 cites W2075491027 @default.
- W2406877987 cites W2076045927 @default.
- W2406877987 cites W2077228161 @default.
- W2406877987 cites W2077792494 @default.
- W2406877987 cites W2077863403 @default.
- W2406877987 cites W2081165863 @default.
- W2406877987 cites W2081292041 @default.
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- W2406877987 cites W2099959898 @default.
- W2406877987 cites W2124058499 @default.
- W2406877987 cites W2142219199 @default.
- W2406877987 cites W2144493631 @default.
- W2406877987 cites W2145931541 @default.
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- W2406877987 cites W2331239786 @default.
- W2406877987 cites W2333578679 @default.
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- W2406877987 cites W2415555 @default.
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- W2406877987 cites W2951717790 @default.
- W2406877987 cites W4290033425 @default.
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- W2406877987 doi "https://doi.org/10.1002/cphc.201600065" @default.
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- W2406877987 hasPublicationYear "2016" @default.
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