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- W2406996940 abstract "The ability to incorporate diverse monomeric building blocks enables the development of advanced polymeric materials possessing a wide range of properties that suits them for myriad applications. Herein, that synthetic toolbox is expanded through the first report of purine-based copolymers in which purines are incorporated directly into the polymer main chain. Stille cross-coupling of dibromopurine monomers with benzodithiophene (BDT) comonomers is used to generate these poly(purine)s, and variations in the substitution pattern of the purine monomer and BDT side-chains provides insight into the role of monomer design on their resultant thermal and photophysical properties. Specifically, thermal analyses show that poly(purine)s exhibit high thermal stability and high glass transition temperatures depending on the BDT side-chain substituents and substitution pattern of the purine-derived comonomer. Furthermore, optical properties measured via UV-vis and fluorescence spectroscopies show dependence on monomer substitution pattern. These findings demonstrate the viability of synthesizing poly(purine)s via metal-catalyzed cross-coupling reactions and highlight the potential to tailor poly(purine) properties via simple alterations of comonomers." @default.
- W2406996940 created "2016-06-24" @default.
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- W2406996940 date "2016-05-17" @default.
- W2406996940 modified "2023-09-26" @default.
- W2406996940 title "Synthesis of Main Chain Purine-Based Copolymers and Effects of Monomer Design on Thermal and Optical Properties" @default.
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- W2406996940 doi "https://doi.org/10.1021/acsmacrolett.6b00275" @default.
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