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- W2408793485 abstract "The reaction of racemic diarylmethylamines, (Ar(1)Ar(2)CHNR2), where Ar(1) is substituted with a 2-hydroxy group, with arylboroxines (Ar(3)BO)3 in the presence of a chiral diene-rhodium catalyst gave high yields of chiral triarylmethanes (Ar(1)Ar(2)CH*Ar(3)) with high enantioselectivity (up to 97% ee). The reaction is assumed to proceed through o-quinone methide intermediates which undergo Rh-catalyzed asymmetric 1,4-addition of the arylboron reagents." @default.
- W2408793485 created "2016-06-24" @default.
- W2408793485 creator A5001880581 @default.
- W2408793485 creator A5027991179 @default.
- W2408793485 date "2015-06-09" @default.
- W2408793485 modified "2023-10-03" @default.
- W2408793485 title "Asymmetric Synthesis of Triarylmethanes by Rhodium-Catalyzed Enantioselective Arylation of Diarylmethylamines with Arylboroxines" @default.
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- W2408793485 doi "https://doi.org/10.1021/jacs.5b03277" @default.
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