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• W2409599634 abstract "The title chiral photochromic Schiff base compound, C21H18BrN3O, was synthesized from (R)-(+)-1-(4-bromo-phen-yl)ethyl-amine and the salicyl-aldehyde of an azo-benzene derivative. The mol-ecule corresponds to the phenol-imine tautomer, the C=N and N-C bond distances being 1.285 (3) and 1.470 (3) Å, respectively. The diazenyl group adopts a trans form, with an N=N distance of 1.256 (3) Å. The hy-droxy group is involved in intra-molecular O-H⋯N hydrogen bonding. In the crystal, C-H⋯π inter-actions consolidate the crystal packing of one-dimensional chains, which exhibits short inter-molecular Br⋯C contacts of 3.400 (3) Å." @default.
• W2409599634 created "2016-06-24" @default.
• W2409599634 creator A5026114984 @default.
• W2409599634 creator A5026163323 @default.
• W2409599634 date "2015-10-28" @default.
• W2409599634 modified "2023-09-26" @default.
• W2409599634 title "Crystal structure of 2-{(<i>R</i>)-[1-(4-bromophenyl)ethyl]iminomethyl}-4-(phenyldiazenyl)phenol, a chiral photochromic Schiff base" @default.
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• W2409599634 doi "https://doi.org/10.1107/s2056989015019866" @default.
• W2409599634 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4645026" @default.
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