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• W2410040269 abstract "Abstract An unprecedented palladium(II)‐catalyzed biomimetic aliphatic acyl (‐COR) group transfer was observed from acyl‐α‐peroxycoumarins to the ortho CH sites of directing arenes. Here, the CH activation is associated with a concomitant acyl group transfer via a Pd(II)‐catalyzed, redox‐neutral process. While methods for ortho aroylation (‐COAr) are well documented ortho acylation (‐COR) processes are scarce, hence the present redox‐neutral method is most ideal for o ‐acylation of directing substrates. magnified image" @default.
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• W2410040269 date "2016-05-31" @default.
• W2410040269 modified "2023-10-18" @default.
• W2410040269 title "Acylperoxycoumarins as<i>ortho</i>-CH Acylating Agent<i>via</i>a Palladium(II)-Catalyzed Redox-Neutral Process" @default.
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• W2410040269 doi "https://doi.org/10.1002/adsc.201600258" @default.
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