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- W2410352730 abstract "the adsorptive desulfurization of thiophene on rapidly quenched skeletal ni (rq ni) was investigated by xps. at 298 k, thiophene in direct contact with rq ni undergoes c-s bond scission, forming metallocycle-like species and atomic sulfur on metallic nickel. further exposure to thiophene leads to physisorbed thiophene. at 373 k, most of the physisorbed thiophene desorbs, with a small portion undergoing sulfur abstraction on the newly exposed nickel surface. the existence of alumina and hydrogen may block the further cracking of the metallocycle-like species at higher temperatures, which has been considered to be the dominant reaction pathway-on ni single crystals. at 473 k, the c-1s peak disappears, leaving nickel sulfide on the surface." @default.
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- W2410352730 date "2006-09-10" @default.
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- W2410352730 title "XPS study on adsorptive desulfurization of thiophene over rapidly quenched skeletal Ni" @default.
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