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- W2410593236 abstract "Metalated nitriles exhibit complementary chemoselectivities in electrophilic alkylations. N-Lithiated or C-magnesiated nitriles can be prepared from the same nitrile precursor and selectively reacted with a 1:1 mixture of methyl cyanoformate and benzyl bromide or bifunctional electrophiles through chemoselective attack onto either an alkyl halide or a carbonyl electrophile. A mechanistic explanation for the chemoselectivity preferences is provided that rests on the structural and complexation differences between N- and C-metalated nitriles." @default.
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- W2410593236 date "2015-09-21" @default.
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- W2410593236 title "Chemoselective Alkylations with <i>N</i>- and <i>C</i>-Metalated Nitriles" @default.
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- W2410593236 doi "https://doi.org/10.1021/acs.orglett.5b02481" @default.
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