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- W2410924910 abstract "Thin films of ${mathrm{ZrO}}_{2}$-${mathrm{Al}}_{2}$${mathrm{O}}_{3}$ were deposited on a variety of substrates by reactive magnetron sputtering. Nucleation and stability of the cubic, tetragonal, and monoclinic phases of ${mathrm{ZrO}}_{2}$ were investigated over the entire composition range. As deposited films were all amorphous. Annealing in air at temperatures up to 1000 ifmmode^circelsetextdegreefi{}C for several hours resulted in the crystallization and evolution of ${mathrm{ZrO}}_{2}$ phases. X-ray diffraction studies suggested that films with [Zr]:[Al] atomic ratios up to 70:30 nucleated first with the zirconia in the cubic phase with subsequent transformation to a tetragonal phase as a function of annealing time. These results are consistent with the recent theoretical predictions that the cubic phase is unstable with respect to tetragonal and orthorhombic phases at lower temperatures. Observed decreases in volume of the monoclinic ${mathrm{ZrO}}_{2}$ phase with increasing ${mathrm{Al}}_{2}$${mathrm{O}}_{3}$ content suggest an internal compression that reduces the volume of the monoclinic cell to that of the tetragonal unit cell, at which point the tetragonal structure is then observed." @default.
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- W2410924910 date "1989-03-15" @default.
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- W2410924910 title "Phase stability of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>ZrO</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn><mml:mi mathvariant=normal>−</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Al</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:…" @default.
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- W2410924910 doi "https://doi.org/10.1103/physrevb.39.6234" @default.
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