Matches in SemOpenAlex for { <https://semopenalex.org/work/W2411480470> ?p ?o ?g. }
- W2411480470 abstract "Chemical functionalization is required to adapt graphenes properties to many applications. However, most covalent functionalization schemes are spontaneous or defect driven and are not suitable for applications requiring directed assembly of molecules on graphene substrates. In this work, we demonstrated electrochemically driven covalent bonding of phenyl iodoniums onto epitaxial graphene. The amount of chemisorption was demonstrated by varying the duration of the electrochemical driving potential. Chemical, electronic, and defect states of phenyl-modified graphene were studied by photoemission spectroscopy, spatially resolved Raman spectroscopy, and water contact angle measurement. Covalent attachment rehybridized some of the delocalized graphene sp2 orbitals to localized sp3 states. Control over the relative spontaneity (reaction rate) of covalent graphene functionalization is an important first step to the practical realization of directed molecular assembly on graphene. More than 10 publications, conference presentations, and program highlights were produced (some invited), and follow-on funding was obtained to continue this work." @default.
- W2411480470 created "2016-06-24" @default.
- W2411480470 creator A5003100398 @default.
- W2411480470 creator A5016780645 @default.
- W2411480470 creator A5020420321 @default.
- W2411480470 creator A5049734305 @default.
- W2411480470 creator A5074871298 @default.
- W2411480470 creator A5078060955 @default.
- W2411480470 creator A5083808939 @default.
- W2411480470 creator A5088934376 @default.
- W2411480470 date "2013-09-01" @default.
- W2411480470 modified "2023-09-26" @default.
- W2411480470 title "Accelerating the development of transparent graphene electrodes through basic science driven chemical functionalization." @default.
- W2411480470 cites W1966681574 @default.
- W2411480470 cites W1972522786 @default.
- W2411480470 cites W1973341977 @default.
- W2411480470 cites W1980526246 @default.
- W2411480470 cites W1990710956 @default.
- W2411480470 cites W1991482062 @default.
- W2411480470 cites W1994403608 @default.
- W2411480470 cites W1997147730 @default.
- W2411480470 cites W1997919745 @default.
- W2411480470 cites W2002075916 @default.
- W2411480470 cites W2002429347 @default.
- W2411480470 cites W2004277091 @default.
- W2411480470 cites W2009752024 @default.
- W2411480470 cites W2014935324 @default.
- W2411480470 cites W2020711856 @default.
- W2411480470 cites W2024296055 @default.
- W2411480470 cites W2036703856 @default.
- W2411480470 cites W2042536398 @default.
- W2411480470 cites W2048109982 @default.
- W2411480470 cites W2052404669 @default.
- W2411480470 cites W2056922191 @default.
- W2411480470 cites W2062885303 @default.
- W2411480470 cites W2065980160 @default.
- W2411480470 cites W2067766166 @default.
- W2411480470 cites W2080360972 @default.
- W2411480470 cites W2084075657 @default.
- W2411480470 cites W2089459394 @default.
- W2411480470 cites W2097773259 @default.
- W2411480470 cites W2099779584 @default.
- W2411480470 cites W2107485045 @default.
- W2411480470 cites W2113228695 @default.
- W2411480470 cites W2121621337 @default.
- W2411480470 cites W2136334331 @default.
- W2411480470 cites W2139301404 @default.
- W2411480470 cites W2140592868 @default.
- W2411480470 cites W2316200154 @default.
- W2411480470 cites W2320963667 @default.
- W2411480470 cites W2329409464 @default.
- W2411480470 cites W2329980432 @default.
- W2411480470 cites W2597242839 @default.
- W2411480470 cites W3141794078 @default.
- W2411480470 cites W2121495438 @default.
- W2411480470 cites W2125203621 @default.
- W2411480470 doi "https://doi.org/10.2172/1177088" @default.
- W2411480470 hasPublicationYear "2013" @default.
- W2411480470 type Work @default.
- W2411480470 sameAs 2411480470 @default.
- W2411480470 citedByCount "0" @default.
- W2411480470 crossrefType "report" @default.
- W2411480470 hasAuthorship W2411480470A5003100398 @default.
- W2411480470 hasAuthorship W2411480470A5016780645 @default.
- W2411480470 hasAuthorship W2411480470A5020420321 @default.
- W2411480470 hasAuthorship W2411480470A5049734305 @default.
- W2411480470 hasAuthorship W2411480470A5074871298 @default.
- W2411480470 hasAuthorship W2411480470A5078060955 @default.
- W2411480470 hasAuthorship W2411480470A5083808939 @default.
- W2411480470 hasAuthorship W2411480470A5088934376 @default.
- W2411480470 hasBestOaLocation W24114804702 @default.
- W2411480470 hasConcept C115537861 @default.
- W2411480470 hasConcept C127413603 @default.
- W2411480470 hasConcept C134306372 @default.
- W2411480470 hasConcept C147789679 @default.
- W2411480470 hasConcept C171250308 @default.
- W2411480470 hasConcept C17525397 @default.
- W2411480470 hasConcept C185592680 @default.
- W2411480470 hasConcept C192562407 @default.
- W2411480470 hasConcept C2776542497 @default.
- W2411480470 hasConcept C30080830 @default.
- W2411480470 hasConcept C33923547 @default.
- W2411480470 hasConcept C42360764 @default.
- W2411480470 hasConceptScore W2411480470C115537861 @default.
- W2411480470 hasConceptScore W2411480470C127413603 @default.
- W2411480470 hasConceptScore W2411480470C134306372 @default.
- W2411480470 hasConceptScore W2411480470C147789679 @default.
- W2411480470 hasConceptScore W2411480470C171250308 @default.
- W2411480470 hasConceptScore W2411480470C17525397 @default.
- W2411480470 hasConceptScore W2411480470C185592680 @default.
- W2411480470 hasConceptScore W2411480470C192562407 @default.
- W2411480470 hasConceptScore W2411480470C2776542497 @default.
- W2411480470 hasConceptScore W2411480470C30080830 @default.
- W2411480470 hasConceptScore W2411480470C33923547 @default.
- W2411480470 hasConceptScore W2411480470C42360764 @default.
- W2411480470 hasLocation W24114804701 @default.
- W2411480470 hasLocation W24114804702 @default.
- W2411480470 hasOpenAccess W2411480470 @default.
- W2411480470 hasPrimaryLocation W24114804701 @default.
- W2411480470 hasRelatedWork W1966493114 @default.