FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2411537103> ?p ?o ?g. }

• W2411537103 endingPage "6010" @default.
• W2411537103 startingPage "6000" @default.
• W2411537103 abstract "There have been a number of recent studies reporting high-spin d4,6 complexes with three- and four-coordinate geometry, which exhibit roughly trigonal symmetry. These include complexes of Fe(II) with general formula L3FeX, where L = thioether or dialkylphosphine donors of a tripodal chelating ligand and X is a monodentate ligand on the C3 axis. In these systems, there is unquenched orbital angular momentum, which has significant consequences on the electronic/magnetic properties of the complexes, including magnetic susceptibility, EPR spectra, and magnetic Mössbauer spectra. We describe here a simple model using a description of the d orbitals with trigonal symmetry that along with the application of the spin–orbit interaction successfully explains the magnetic properties of such systems. These d orbitals with 3-fold symmetry are complex orbitals with a parameter, a, that is determined by the bond angle, α, of LFeX. We demonstrate that the E symmetry states in such systems with S > 1/2 cannot be properly “simulated by” or be “represented by” the Zeeman and second-order zero-field spin Hamiltonian alone because by definition the parameters D and E are second-order terms. One must include the first-order spin–orbit interaction. We also find these systems to be very anisotropic in all their magnetic properties. For example, the perpendicular values of g and the hyperfine interaction parameter are essentially zero for the ground-state doublet. For illustrative purposes, the discussion focuses primarily on two specific Fe(II) complexes: one with the bond angle α greater than tetrahedral and another with the bond angle α less than tetrahedral. The nature of the EPR spectra and hyperfine interaction of 57Fe are discussed." @default.
• W2411537103 created "2016-06-24" @default.
• W2411537103 creator A5000558729 @default.
• W2411537103 creator A5081072389 @default.
• W2411537103 date "2012-05-14" @default.
• W2411537103 modified "2023-10-15" @default.
• W2411537103 title "Simple Ligand-Field Theory of <i>d</i>⁴ and <i>d</i>⁶ Transition Metal Complexes with a <i>C</i>₃ Symmetry Axis" @default.
• W2411537103 cites W1546333162 @default.
• W2411537103 cites W1966229941 @default.
• W2411537103 cites W1967700647 @default.
• W2411537103 cites W1970592794 @default.
• W2411537103 cites W1972244400 @default.
• W2411537103 cites W1980905694 @default.
• W2411537103 cites W1988271639 @default.
• W2411537103 cites W1992999739 @default.
• W2411537103 cites W1997779485 @default.
• W2411537103 cites W1999245421 @default.
• W2411537103 cites W1999631653 @default.
• W2411537103 cites W2003618810 @default.
• W2411537103 cites W2013903780 @default.
• W2411537103 cites W2015121114 @default.
• W2411537103 cites W2022742403 @default.
• W2411537103 cites W2023540707 @default.
• W2411537103 cites W2041424600 @default.
• W2411537103 cites W2046343800 @default.
• W2411537103 cites W2065290596 @default.
• W2411537103 cites W2066099283 @default.
• W2411537103 cites W2079927575 @default.
• W2411537103 cites W2081689950 @default.
• W2411537103 cites W2082174525 @default.
• W2411537103 cites W2083079706 @default.
• W2411537103 cites W2084083512 @default.
• W2411537103 cites W2084546957 @default.
• W2411537103 cites W2091156628 @default.
• W2411537103 cites W2129652151 @default.
• W2411537103 cites W2160187350 @default.
• W2411537103 cites W2328907905 @default.
• W2411537103 cites W2949895871 @default.
• W2411537103 doi "https://doi.org/10.1021/ic201189a" @default.
• W2411537103 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22583045" @default.
• W2411537103 hasPublicationYear "2012" @default.
• W2411537103 type Work @default.
• W2411537103 sameAs 2411537103 @default.
• W2411537103 citedByCount "40" @default.
• W2411537103 countsByYear W24115371032013 @default.
• W2411537103 countsByYear W24115371032014 @default.
• W2411537103 countsByYear W24115371032015 @default.
• W2411537103 countsByYear W24115371032016 @default.
• W2411537103 countsByYear W24115371032017 @default.
• W2411537103 countsByYear W24115371032018 @default.
• W2411537103 countsByYear W24115371032020 @default.
• W2411537103 countsByYear W24115371032021 @default.
• W2411537103 countsByYear W24115371032022 @default.
• W2411537103 countsByYear W24115371032023 @default.
• W2411537103 crossrefType "journal-article" @default.
• W2411537103 hasAuthorship W2411537103A5000558729 @default.
• W2411537103 hasAuthorship W2411537103A5081072389 @default.
• W2411537103 hasConcept C115260700 @default.
• W2411537103 hasConcept C121332964 @default.
• W2411537103 hasConcept C131538251 @default.
• W2411537103 hasConcept C145148216 @default.
• W2411537103 hasConcept C147120987 @default.
• W2411537103 hasConcept C178790620 @default.
• W2411537103 hasConcept C184779094 @default.
• W2411537103 hasConcept C185592680 @default.
• W2411537103 hasConcept C189394030 @default.
• W2411537103 hasConcept C25227350 @default.
• W2411537103 hasConcept C57805442 @default.
• W2411537103 hasConcept C62520636 @default.
• W2411537103 hasConcept C8010536 @default.
• W2411537103 hasConceptScore W2411537103C115260700 @default.
• W2411537103 hasConceptScore W2411537103C121332964 @default.
• W2411537103 hasConceptScore W2411537103C131538251 @default.
• W2411537103 hasConceptScore W2411537103C145148216 @default.
• W2411537103 hasConceptScore W2411537103C147120987 @default.
• W2411537103 hasConceptScore W2411537103C178790620 @default.
• W2411537103 hasConceptScore W2411537103C184779094 @default.
• W2411537103 hasConceptScore W2411537103C185592680 @default.
• W2411537103 hasConceptScore W2411537103C189394030 @default.
• W2411537103 hasConceptScore W2411537103C25227350 @default.
• W2411537103 hasConceptScore W2411537103C57805442 @default.
• W2411537103 hasConceptScore W2411537103C62520636 @default.
• W2411537103 hasConceptScore W2411537103C8010536 @default.
• W2411537103 hasIssue "11" @default.
• W2411537103 hasLocation W24115371031 @default.
• W2411537103 hasLocation W24115371032 @default.
• W2411537103 hasOpenAccess W2411537103 @default.
• W2411537103 hasPrimaryLocation W24115371031 @default.
• W2411537103 hasRelatedWork W1965616406 @default.
• W2411537103 hasRelatedWork W1965836485 @default.
• W2411537103 hasRelatedWork W1977979407 @default.
• W2411537103 hasRelatedWork W2024239230 @default.
• W2411537103 hasRelatedWork W2033046343 @default.
• W2411537103 hasRelatedWork W2059956798 @default.
• W2411537103 hasRelatedWork W2063482341 @default.
• W2411537103 hasRelatedWork W2091833132 @default.
• W2411537103 hasRelatedWork W3144430943 @default.
• W2411537103 hasRelatedWork W4238066748 @default.

• next