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- W2411596572 abstract "Abstract Ag-containing compounds are regarded as potential candidates for the efficient photocatalyst driven by visible-light. In this work, nano-sized Ag2CaV4O12 was prepared via a modified Pechini synthesis. The detailed structural refinement of X-ray diffraction (XRD) pattern indicates that the Ag2CaV4O12 crystallizes in tetragonal system with the space group of P4/nbm (125), Z = 2. The surface property of this vanadate was measured by the scanning electron microscope (SEM), energy dispersive spectra (EDS), transmission electron microscopy (TEM), and nitrogen adsorption-desorption isotherm. The sample has an efficient optical absorption in the wavelength from UV to visible region characterized by its narrow band-gap energy of 2.231 eV with an indirect allowed property. The valence band maximum is composed of multiple states of Ag-d and O-p resulting in a narrow band. The excellent photocatalytic activity of Ag2CaV4O12 nanoparticles was tested by the photodegradation of rhodamine B (RhB), methylene blue (MB) and phenol solutions excited by visible-light. The photocatalytic mechanism was suggested according to experimental results and the band energy positions." @default.
- W2411596572 created "2016-06-24" @default.
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- W2411596572 date "2016-09-01" @default.
- W2411596572 modified "2023-09-24" @default.
- W2411596572 title "Synthesis, surface and optical properties of Ag2CaV4O12 nanoparticles for dye removal under visible irradiation" @default.
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- W2411596572 doi "https://doi.org/10.1016/j.matchemphys.2016.06.006" @default.
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