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• W2411642735 endingPage "9451" @default.
• W2411642735 startingPage "9444" @default.
• W2411642735 abstract "Cesium bis(perfluoro-triphenylborane)amide, Cs[H2NB2(C6F5)6] (1), has been prepared by the reaction of sodium salt and CsF in dichloromethane and water. The compound is exceptional for a [H2NB2(C6F5)6]− salt in that it contains a monatomic solute-free cation. Determination of the molecular structure revealed a novel C2 symmetrical conformation of the weakly coordinating [H2NB2(C6F5)6]− anion, which gives rise to an unprecedented 16-coordinate (CN 16) Cs+ cation in a likewise unprecedented tetracosahedral arrangement of F atoms. The poor solubility of 1 allows nearly quantitative separation of Cs+ from water, which suggests potential applications as an effective 134/137Cs remover from nuclear waste solutions, administration as an antidote for 134/137Cs poisoning, and use for 131/137Cs radiotherapy (brachytherapy). Rb[H2NB2(C6F5)6]·CH2Cl2 (2) has also been characterized, featuring two inequivalent Rb+ cations having CN 10, one of which involves Rb+(η2-Cl2CH2)2 coordination." @default.
• W2411642735 created "2016-06-24" @default.
• W2411642735 creator A5037346929 @default.
• W2411642735 creator A5069645974 @default.
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• W2411642735 date "2016-06-17" @default.
• W2411642735 modified "2023-10-01" @default.
• W2411642735 title "Cs[H₂NB₂(C₆F₅)₆] Featuring an Unequivocal 16-Coordinate Cation" @default.
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• W2411642735 doi "https://doi.org/10.1021/jacs.6b02590" @default.
• W2411642735 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27267866" @default.
• W2411642735 hasPublicationYear "2016" @default.
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