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• W2412739282 startingPage "5270" @default.
• W2412739282 abstract "A highly efficient asymmetric Mannich reaction of 3-monosubstituted 3-aminooxindoles/3-hydroxyoxindoles with in situ generated N-Boc-protected aldimines catalyzed by the chiral bifunctional thiourea–tertiary amine catalyst has been developed. Under mild reaction conditions, a series of structurally diverse vicinal oxindole–diamines/amino alcohols were smoothly obtained in moderate to high yields (up to 99%) with good to excellent diastereoselectivities and enantioselectivities (up to 95:5 dr and 96% ee). The synthetic application of this protocol was also demonstrated by the versatile transformation of chiral vicinal oxindole–diamine/amino alcohol into spirocyclic oxindoles." @default.
• W2412739282 created "2016-06-24" @default.
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• W2412739282 date "2016-06-21" @default.
• W2412739282 modified "2023-09-24" @default.
• W2412739282 title "Organocatalytic Asymmetric Mannich Reaction of 3-Hydroxyoxindoles/3-Aminooxindoles with in Situ Generated <i>N</i>-Boc-Protected Aldimines for the Synthesis of Vicinal Oxindole–Diamines/Amino Alcohols" @default.
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• W2412739282 doi "https://doi.org/10.1021/acs.joc.6b00278" @default.
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