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• W2412966497 abstract "In situ AC nanocalorimetry was used to measure the reversing heat capacity of vapor-deposited glasses of decahydronaphthalene (decalin). Glasses with low heat capacity and high kinetic stability, as compared to the corresponding liquid-cooled glass, were prepared from cis-decalin and from several cis/trans-decalin mixtures. This is the first report of highly stable glass formation for molecular mixtures. The 50/50 cis/trans-decalin mixture is the highest fragility material reported to produce an ultrastable glass. The 50/50 mixture exhibited high kinetic stability, with a ∼500 nm film deposited at 116 K (0.86 Tg) displaying a transformation time equivalent to 104.4 times the structural relaxation time of the supercooled liquid at the annealing temperature. cis-Decalin and the decalin mixture formed stable glasses that had heat capacities as much as 4.5% lower than the liquid-cooled glass." @default.
• W2412966497 created "2016-06-24" @default.
• W2412966497 creator A5000299760 @default.
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• W2412966497 creator A5072039182 @default.
• W2412966497 date "2013-06-12" @default.
• W2412966497 modified "2023-10-10" @default.
• W2412966497 title "Highly Stable Glasses of <i>cis</i>-Decalin and <i>cis</i>/<i>trans</i>-Decalin Mixtures" @default.
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• W2412966497 doi "https://doi.org/10.1021/jp400960g" @default.
• W2412966497 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23718270" @default.
• W2412966497 hasPublicationYear "2013" @default.
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