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- W2413028162 abstract "The off-gassing of carbon monoxide (CO) from stored wood pellets has been identified as a significant problem, potentially resulting in adverse occupational and residential exposures. The mechanism for the production of CO from wood pellets has not been fully identified. In this study, a multiple step process has been hypothesized. The reaction is initiated by the autoxidation of unsaturated compounds, including fatty acids and terpenes, by molecular oxygen. As a byproduct of these reactions, hydroxyl radicals are formed. Then, the bulk of CO results from the reactions of hemicellulose and hydroxyl radicals. To understand the mechanistic pathway of CO off-gassing, a number of experiments were conducted in which CO was measured and evolved organic compounds were analyzed using gas chromatography–mass spectrometry (GC–MS). These studies identified a number of short- and long-chain aldehydes from the evolved gases that indicates the autoxidation mechanism. However, there is insufficient mass of these unsaturated compounds in wood to support the observed mass of off-gassed CO. However, autoxidation would form hydroxyl radicals. The role of hydroxyl radicals was investigated using a radical scavenger, and its role in CO production was confirmed. Thus, if the autoxidation initiation can be eliminated, then CO off-gassing from pellets would be substantially reduced. Destruction of the reactive compounds with ozone led to a suppression of CO formation, suggesting an approach to process the wood fiber that would result in low or no CO emission wood pellets." @default.
- W2413028162 created "2016-06-24" @default.
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- W2413028162 date "2016-06-14" @default.
- W2413028162 modified "2023-10-02" @default.
- W2413028162 title "Mechanistic Pathway of Carbon Monoxide Off-Gassing from Wood Pellets" @default.
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- W2413028162 doi "https://doi.org/10.1021/acs.energyfuels.6b00874" @default.
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