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- W2413285732 abstract "Metabolic activation of a tryptophan pyrolysate, 3-amino-1-methyl-5H-pyrido[4,3-b]indole (Trp-P-2) by liver microsomes was studied. Trp-P-2 was converted to at least four metabolites (M-1 to M-4), which were separable by HPLC or TLC. Among them, the major metabolite (M-3) was extremely mutagenic to Salmonella typhimurium TA 98 in the absence of activating enzymes and the activity accounted for almost all mutagenic effects of Trp-P-2. Metabolite M-3 was identified as 3-hydroxyamino-1-methyl-5H-pyrido[4,3-b]indole by mass spectrometry and by conversion to the 4-chloro derivative of Trp-P-2 by treatment with hydrochloric acid. The latter compound was identified by NMR and mass spectrometry." @default.
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- W2413285732 date "1981-05-01" @default.
- W2413285732 modified "2023-10-16" @default.
- W2413285732 title "Structural elucidation of a mutagenic metabolite of 3-amino-1-methyl-5H-pyrido[4,3-b]indole." @default.
- W2413285732 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/6113943" @default.
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