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- W2413305749 abstract "After incubation of 1,3,5(10),16-oestratetraenol, a 16-dehydrosteroid, with rat liver microsomes, 16 alpha, 17 alpha-epoxy-oestratrienol was isolated as metabolite. The compound was detected by the use of mass fragmentography after purification of the incubation extract by thin-layer chromatography. Since the epoxide is rapidly hydrolysed by a hepatic epoxide hydratase, only very small concentrations of this metabolite were present in the incubation extract. When styrene oxide was added to the incubation mixture as inhibitor of the epoxide hydratase, the yield of the steroid epoxide increased considerably. Final identification of the oestrogen epoxide was performed by recording mass spectra and by comparison with authentic reference material." @default.
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- W2413305749 date "1980-09-01" @default.
- W2413305749 modified "2023-09-23" @default.
- W2413305749 title "Biosynthesis of 16 alpha, 17 alpha-epoxy-oestratrienol in rat liver microsomes." @default.
- W2413305749 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/7456972" @default.
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