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• W2413891320 startingPage "2926" @default.
• W2413891320 abstract "The synthesis of constrained spirocycles is achieved effectively by means of 1,3-dipolar cyclodditions employing α-imino γ-lactones as azomethine ylide precursors and nitroalkenes as dipolarophiles. The complex formed by (R,R)-Me-DuPhos 18 and AgF is the most efficient bifunctional catalyst. Final spiro-nitroprolinates cycloadducts are obtained in good to moderate yields and both high diastereo- and enantioselectivities. Density functional theory (DFT) calculations supported the expected absolute configuration as well as other stereochemical parameters." @default.
• W2413891320 created "2016-06-24" @default.
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• W2413891320 date "2016-06-08" @default.
• W2413891320 modified "2023-10-18" @default.
• W2413891320 title "Enantioselective Synthesis of Polysubstituted Spiro-nitroprolinates Mediated by a (<i>R</i>,<i>R</i>)-Me-DuPhos·AgF-Catalyzed 1,3-Dipolar Cycloaddition" @default.
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• W2413891320 doi "https://doi.org/10.1021/acs.orglett.6b01273" @default.
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