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- W2414015977 abstract "Total syntheses of cassiarins A and B have been efficiently accomplished using a common strategy with biomimetic considerations. Key reactions involved in this synthesis include a Negishi-type coupling, a Ag(I)-promoted formation of the tricyclic 8H-pyrano[2,3,4-de]chromen-8-one core, and a sequential amine-condensation and cyclization. Three new analogues of cassiarin A hearing different substituents at the C-11 position were synthesized in parallel from the same intermediate. In addition, two other transformations to the key tricyclic cores and cassiarins A and B were achieved from corresponding chemically equivalent precursors." @default.
- W2414015977 created "2016-06-24" @default.
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- W2414015977 date "2008-01-01" @default.
- W2414015977 modified "2023-09-27" @default.
- W2414015977 title "Biomimetic total syntheses of cassiarins A and B" @default.
- W2414015977 hasPublicationYear "2008" @default.
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