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- W2414081640 endingPage "8574" @default.
- W2414081640 startingPage "8571" @default.
- W2414081640 abstract "Abstract The tripeptide H‐ d Pro‐Pro‐Asn‐NH 2 is presented as a catalyst for asymmetric conjugate addition reactions of aldehydes to maleimide. The peptidic catalyst promotes the reaction between various aldehydes and unprotected maleimide with high stereoselectivities and yields. The obtained products were readily derivatized to the corresponding pyrrolidines, lactams, lactones, and peptide‐like compounds. 1 H NMR spectroscopic, crystallographic, and computational investigations provided insight into the conformational properties of H‐ d Pro‐Pro‐Asn‐NH 2 and revealed the importance of hydrogen bonding between the peptide and maleimide for catalyzing the stereoselective C−C bond formation." @default.
- W2414081640 created "2016-06-24" @default.
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- W2414081640 date "2016-06-02" @default.
- W2414081640 modified "2023-10-14" @default.
- W2414081640 title "Peptide-Catalyzed Stereoselective Conjugate Addition Reactions of Aldehydes to Maleimide" @default.
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- W2414081640 doi "https://doi.org/10.1002/anie.201602230" @default.
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