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- W2414094219 endingPage "8974" @default.
- W2414094219 startingPage "8970" @default.
- W2414094219 abstract "Abstract A new BINOL‐derived chiral phosphoric acid bearing 2,4,6‐trimethyl‐3,5‐dinitrophenyl substituents at the 3,3′‐positions was developed. The utility of this chiral phosphoric acid is demonstrated by a highly enantioselective ( ee up to >99 %) and diastereoselective ( syn / anti up to >99:1) asymmetric Mukaiyama–Mannich reaction of imines with a wide range of ketene silyl acetals. Moreover, this method was successfully applied to the construction of vicinal tertiary and quaternary stereogenic centers with excellent diastereo‐ and enantioselectivity. Significantly, BINOL‐derived N ‐triflyl phosphoramide constitutes a complementary catalyst system that allows the title reaction to be applied to more challenging imines without an N‐( 2‐hydroxyphenyl) moiety." @default.
- W2414094219 created "2016-06-24" @default.
- W2414094219 creator A5028679667 @default.
- W2414094219 creator A5038686832 @default.
- W2414094219 date "2016-06-06" @default.
- W2414094219 modified "2023-10-12" @default.
- W2414094219 title "A Powerful Chiral Phosphoric Acid Catalyst for Enantioselective Mukaiyama-Mannich Reactions" @default.
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- W2414094219 doi "https://doi.org/10.1002/anie.201603929" @default.
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