Matches in SemOpenAlex for { <https://semopenalex.org/work/W2414181531> ?p ?o ?g. }
Showing items 1 to 76 of
76
with 100 items per page.
- W2414181531 endingPage "92" @default.
- W2414181531 startingPage "83" @default.
- W2414181531 abstract "The interaction between methemoglobin (MetHb) and macroporous matrices on the basis of polymethacrylates was investigated by means of optical and e.p.r. spectroscopy. The spectroscopic data show that the adsorption of MetHb to imidazole-containing matrices occurs by complex formation between matrix-bound imidazole and the iron of the prosthetic group, with all 4 polypeptide chains of the MetHb molecule being included in the interaction. The adsorption to hydrophobic side chains containing matrices leads, via the protein-matrix interaction, to considerable disturbances of iron protoporphyrin IX in equilibrium or formed from protein-contacts, which are of general importance with respect to the functional variablity and control, respectively, of iron porphyrins in hemoproteins. In case of matrix containing n-hexyl groups deoxyHb is oxidized by O2 to MetHb, instead of being oxygenated to HbO2. Not all prosthetic groups are able to bind N-3. With the increase in hydrophobicity of the matrix a conformational change is enforced leading in the beta-chains to the direct interaction between iron and sulfur of cysteine (beta-cys 92), as it is proved in all cytochrome P-450 and other model compounds." @default.
- W2414181531 created "2016-06-24" @default.
- W2414181531 creator A5004377408 @default.
- W2414181531 creator A5014099810 @default.
- W2414181531 creator A5040696653 @default.
- W2414181531 creator A5046637013 @default.
- W2414181531 creator A5050108344 @default.
- W2414181531 creator A5015980714 @default.
- W2414181531 date "1980-01-01" @default.
- W2414181531 modified "2023-09-27" @default.
- W2414181531 title "[The interaction of methemoglobin and modified poly-(hydroxyethylmethacrylates) studied by spectroscopic methods]." @default.
- W2414181531 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/6252740" @default.
- W2414181531 hasPublicationYear "1980" @default.
- W2414181531 type Work @default.
- W2414181531 sameAs 2414181531 @default.
- W2414181531 citedByCount "0" @default.
- W2414181531 crossrefType "journal-article" @default.
- W2414181531 hasAuthorship W2414181531A5004377408 @default.
- W2414181531 hasAuthorship W2414181531A5014099810 @default.
- W2414181531 hasAuthorship W2414181531A5015980714 @default.
- W2414181531 hasAuthorship W2414181531A5040696653 @default.
- W2414181531 hasAuthorship W2414181531A5046637013 @default.
- W2414181531 hasAuthorship W2414181531A5050108344 @default.
- W2414181531 hasConcept C106487976 @default.
- W2414181531 hasConcept C150394285 @default.
- W2414181531 hasConcept C178790620 @default.
- W2414181531 hasConcept C181199279 @default.
- W2414181531 hasConcept C185592680 @default.
- W2414181531 hasConcept C188027245 @default.
- W2414181531 hasConcept C20705724 @default.
- W2414181531 hasConcept C26865036 @default.
- W2414181531 hasConcept C2776217839 @default.
- W2414181531 hasConcept C2778917026 @default.
- W2414181531 hasConcept C2780874372 @default.
- W2414181531 hasConcept C32909587 @default.
- W2414181531 hasConcept C43617362 @default.
- W2414181531 hasConcept C71240020 @default.
- W2414181531 hasConcept C75473681 @default.
- W2414181531 hasConcept C8010536 @default.
- W2414181531 hasConceptScore W2414181531C106487976 @default.
- W2414181531 hasConceptScore W2414181531C150394285 @default.
- W2414181531 hasConceptScore W2414181531C178790620 @default.
- W2414181531 hasConceptScore W2414181531C181199279 @default.
- W2414181531 hasConceptScore W2414181531C185592680 @default.
- W2414181531 hasConceptScore W2414181531C188027245 @default.
- W2414181531 hasConceptScore W2414181531C20705724 @default.
- W2414181531 hasConceptScore W2414181531C26865036 @default.
- W2414181531 hasConceptScore W2414181531C2776217839 @default.
- W2414181531 hasConceptScore W2414181531C2778917026 @default.
- W2414181531 hasConceptScore W2414181531C2780874372 @default.
- W2414181531 hasConceptScore W2414181531C32909587 @default.
- W2414181531 hasConceptScore W2414181531C43617362 @default.
- W2414181531 hasConceptScore W2414181531C71240020 @default.
- W2414181531 hasConceptScore W2414181531C75473681 @default.
- W2414181531 hasConceptScore W2414181531C8010536 @default.
- W2414181531 hasIssue "1" @default.
- W2414181531 hasLocation W24141815311 @default.
- W2414181531 hasOpenAccess W2414181531 @default.
- W2414181531 hasPrimaryLocation W24141815311 @default.
- W2414181531 hasRelatedWork W1601541965 @default.
- W2414181531 hasRelatedWork W1982384920 @default.
- W2414181531 hasRelatedWork W1990512618 @default.
- W2414181531 hasRelatedWork W2046769463 @default.
- W2414181531 hasRelatedWork W2050808395 @default.
- W2414181531 hasRelatedWork W2081278910 @default.
- W2414181531 hasRelatedWork W2120765298 @default.
- W2414181531 hasRelatedWork W2412415091 @default.
- W2414181531 hasRelatedWork W2414181531 @default.
- W2414181531 hasRelatedWork W3180470198 @default.
- W2414181531 hasVolume "39" @default.
- W2414181531 isParatext "false" @default.
- W2414181531 isRetracted "false" @default.
- W2414181531 magId "2414181531" @default.
- W2414181531 workType "article" @default.