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- W2414286084 abstract "Nitric oxide is an efficient catalyst for the cis-trans (E/Z) isomerization of diazenes. We compare the effect of room temperature solutions bearing low concentrations of nitric oxide, nitrogen dioxide, or oxygen on the rate of cis-trans isomerization, CTI, of the alkene bond in stilbene and on the azo double bond in azobenzene, as well as in four azo derivatives as measured by UV-vis spectroscopy. These rate enhancements can be as large as 3 orders of magnitude for azobenzene in solution. A mechanism is proposed where catalysis is promoted by the interaction of the nitric oxide with the diazene nitrogen lone pairs. Density functional theory, B3LYP/6-311++g** suggests that the binding of NO to the diazene should be weak and reversible but that its NO adduct has an E/Z isomerization barrier of 7.5 kcal/mol." @default.
- W2414286084 created "2016-06-24" @default.
- W2414286084 creator A5006219355 @default.
- W2414286084 creator A5090648741 @default.
- W2414286084 date "2015-07-22" @default.
- W2414286084 modified "2023-09-24" @default.
- W2414286084 title "Nitric Oxide Catalysis of Diazene<i>E</i>/<i>Z</i>Isomerization" @default.
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- W2414286084 doi "https://doi.org/10.1021/acs.inorgchem.5b00476" @default.
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- W2414286084 hasPublicationYear "2015" @default.
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