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- W2414340314 abstract "The catalytic hydrogenation of sodium oleate in emulsion form was carried out using the second-generation Ru Hoveyda–Grubbs catalyst in a semibatch reactor. A fast and complete hydrogenation of the C═C bond was observed after a reaction time of 1 h with 0.4 wt % catalyst at 120 °C and 8.27 MPa hydrogen gas. 1H NMR characterization shows that the carboxylic group C═O was preserved without any reduction. The hydrogenated product sodium stearate was thus obtained. Our results show that the Hoveyda–Grubbs second-generation catalyst can maintain its activity for the hydrogenation reactions in an organic solvent free environment. The hydrogenation reaction presented here provides an alternate pathway to manufacture sodium stearate and other saturated fatty acid salts in a greater volume by an environmental friendly “green” process. In addition, this research will benefit the commercial process of catalytic hydrogenation of unsaturated elastomers in latex form." @default.
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- W2414340314 date "2016-06-16" @default.
- W2414340314 modified "2023-10-14" @default.
- W2414340314 title "Hydrogenation of Sodium Oleate in Aqueous Emulsion with the Hoveyda–Grubbs Second-Generation Catalyst" @default.
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- W2414340314 doi "https://doi.org/10.1021/acs.oprd.6b00074" @default.
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