Matches in SemOpenAlex for { <https://semopenalex.org/work/W2414706532> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W2414706532 endingPage "1925" @default.
- W2414706532 startingPage "1918" @default.
- W2414706532 abstract "Families of amphiphilic oxidation‐responsive polymers (poly(ethylene glycol)‐polysulfides) with different architectures (linear, 4, 6, and 8‐armed stars and 10, 15, and 20‐armed combs) and compositions (variable ethylene sulfide/propylene sulfide ratio) are prepared. In water, all the polymers assemble in spherical micelles, with critical micellar concentrations <0.01 mg mL −1 for all the branched polymers. Triple‐detection gel permeation chromatography (GPC) and asymmetric field flow fractionation (AFFF) with dynamic and static light scattering detection, respectively, show an increasing compaction of the polymeric coil and a strong reduction of the aggregation number with increasing degree of branching. The key finding of this study is that the kinetics of the oxidative response sharply depend on the branching; in particular, it is highlighted that the degree of branching influences the lag time before a response can be observed rather than the speed of the response itself, a phenomenon that is attributed to a branching‐dependent solubility of the oxidant in the polysulfide matrix. image" @default.
- W2414706532 created "2016-06-24" @default.
- W2414706532 creator A5006495466 @default.
- W2414706532 creator A5045923701 @default.
- W2414706532 creator A5075693768 @default.
- W2414706532 creator A5091176143 @default.
- W2414706532 date "2016-09-27" @default.
- W2414706532 modified "2023-09-26" @default.
- W2414706532 title "Linear, Star, and Comb Oxidation-Responsive Polymers: Effect of Branching Degree and Topology on Aggregation and Responsiveness" @default.
- W2414706532 cites W1965015255 @default.
- W2414706532 cites W2007517884 @default.
- W2414706532 cites W2008648326 @default.
- W2414706532 cites W2011799314 @default.
- W2414706532 cites W2022549879 @default.
- W2414706532 cites W2059486762 @default.
- W2414706532 cites W2060799998 @default.
- W2414706532 cites W2074232728 @default.
- W2414706532 cites W2108389687 @default.
- W2414706532 cites W2117289416 @default.
- W2414706532 cites W2130495733 @default.
- W2414706532 cites W2132118277 @default.
- W2414706532 cites W2145121515 @default.
- W2414706532 cites W2145620844 @default.
- W2414706532 cites W2149011637 @default.
- W2414706532 cites W2239780481 @default.
- W2414706532 cites W2323115574 @default.
- W2414706532 cites W2330828932 @default.
- W2414706532 cites W2513101552 @default.
- W2414706532 doi "https://doi.org/10.1002/marc.201600481" @default.
- W2414706532 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27676076" @default.
- W2414706532 hasPublicationYear "2016" @default.
- W2414706532 type Work @default.
- W2414706532 sameAs 2414706532 @default.
- W2414706532 citedByCount "18" @default.
- W2414706532 countsByYear W24147065322017 @default.
- W2414706532 countsByYear W24147065322018 @default.
- W2414706532 countsByYear W24147065322019 @default.
- W2414706532 countsByYear W24147065322021 @default.
- W2414706532 countsByYear W24147065322022 @default.
- W2414706532 countsByYear W24147065322023 @default.
- W2414706532 crossrefType "journal-article" @default.
- W2414706532 hasAuthorship W2414706532A5006495466 @default.
- W2414706532 hasAuthorship W2414706532A5045923701 @default.
- W2414706532 hasAuthorship W2414706532A5075693768 @default.
- W2414706532 hasAuthorship W2414706532A5091176143 @default.
- W2414706532 hasConcept C11268172 @default.
- W2414706532 hasConcept C127413603 @default.
- W2414706532 hasConcept C14631669 @default.
- W2414706532 hasConcept C155672457 @default.
- W2414706532 hasConcept C171250308 @default.
- W2414706532 hasConcept C178790620 @default.
- W2414706532 hasConcept C184651966 @default.
- W2414706532 hasConcept C185592680 @default.
- W2414706532 hasConcept C188027245 @default.
- W2414706532 hasConcept C192562407 @default.
- W2414706532 hasConcept C206175624 @default.
- W2414706532 hasConcept C2777516009 @default.
- W2414706532 hasConcept C42360764 @default.
- W2414706532 hasConcept C521977710 @default.
- W2414706532 hasConceptScore W2414706532C11268172 @default.
- W2414706532 hasConceptScore W2414706532C127413603 @default.
- W2414706532 hasConceptScore W2414706532C14631669 @default.
- W2414706532 hasConceptScore W2414706532C155672457 @default.
- W2414706532 hasConceptScore W2414706532C171250308 @default.
- W2414706532 hasConceptScore W2414706532C178790620 @default.
- W2414706532 hasConceptScore W2414706532C184651966 @default.
- W2414706532 hasConceptScore W2414706532C185592680 @default.
- W2414706532 hasConceptScore W2414706532C188027245 @default.
- W2414706532 hasConceptScore W2414706532C192562407 @default.
- W2414706532 hasConceptScore W2414706532C206175624 @default.
- W2414706532 hasConceptScore W2414706532C2777516009 @default.
- W2414706532 hasConceptScore W2414706532C42360764 @default.
- W2414706532 hasConceptScore W2414706532C521977710 @default.
- W2414706532 hasFunder F4320307770 @default.
- W2414706532 hasFunder F4320320291 @default.
- W2414706532 hasIssue "23" @default.
- W2414706532 hasLocation W24147065321 @default.
- W2414706532 hasLocation W24147065322 @default.
- W2414706532 hasOpenAccess W2414706532 @default.
- W2414706532 hasPrimaryLocation W24147065321 @default.
- W2414706532 hasRelatedWork W1967480643 @default.
- W2414706532 hasRelatedWork W2006921898 @default.
- W2414706532 hasRelatedWork W2044672187 @default.
- W2414706532 hasRelatedWork W2102321661 @default.
- W2414706532 hasRelatedWork W2120162732 @default.
- W2414706532 hasRelatedWork W2123070170 @default.
- W2414706532 hasRelatedWork W2314314165 @default.
- W2414706532 hasRelatedWork W2370003168 @default.
- W2414706532 hasRelatedWork W2551670042 @default.
- W2414706532 hasRelatedWork W2889194851 @default.
- W2414706532 hasVolume "37" @default.
- W2414706532 isParatext "false" @default.
- W2414706532 isRetracted "false" @default.
- W2414706532 magId "2414706532" @default.
- W2414706532 workType "article" @default.