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- W2414972629 abstract "Abstract Composite poly(ionic liquid)-ionic liquid membranes containing copper (I) chloride (CuCl) have been successfully fabricated via photopolymerization of an IL monomer, 1-vinyl-3-butylimidazolium bistriflimide ([C4vim][Tf2N]), in the presence of CuCl and a non-polymerizable IL, 1-butyl-3-methylimidazolium chloride ([C4mim][Cl]), forming the chlorocuprate anion ([CuCl2]−) in situ. The influence of the metal salt content on the gas separation performance of the composite membranes was assessed. Results showed that increasing the content of non-polymerizable IL enhanced the permeabilities of CO2, H2, N2 and CO relative to those obtained in the pristine poly([C4vim][Tf2N]); whereas the addition of CuCl induced a general reduction of gas diffusivity. On the whole, an enhancement of both gas permeability and ideal gas pair selectivity were observed for CO2/N2 and H2/N2 separations in the Cu-containing composite membranes with respect to the neat poly([C4vim][Tf2N])." @default.
- W2414972629 created "2016-06-24" @default.
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- W2414972629 date "2016-10-01" @default.
- W2414972629 modified "2023-10-03" @default.
- W2414972629 title "Synthesis and gas separation properties of poly(ionic liquid)-ionic liquid composite membranes containing a copper salt" @default.
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- W2414972629 doi "https://doi.org/10.1016/j.memsci.2016.05.045" @default.
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