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- W2415248082 abstract "A kinetic study of oxidation of procaine hydrochloride (one of the potent local anaesthetics) by sodium N-chlorobenzenesulfonamide (chloramine-B or CAB) has been carried out in HClO 4 (30°C) and NaOH (20°C) media. In acid medium, the rate shows first-order dependence on CAB o and fractional-order dependence on substrate o. But, it is independent of the acid. In alkaline medium, the rate exhibits first-order dependence each on CAB o and substrate o, and inverse fractional-order on OH -. Activation parameters have been evaluated. The reaction is found to be faster in alkaline medium in comparison with acid medium. The conjugate free acid C 6H 5SO 2NHCl of CAB is postulated as the reactive oxidizing species in both the media. The observed results have been explained by plausible mechanisms and the related rate laws have been deduced." @default.
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- W2415248082 date "2006-11-01" @default.
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- W2415248082 title "Kinetics of oxidation of procaine hydrochloride by sodium N-chlorobenzenesulfonamide in acid and alkaline media: A mechanistic approach" @default.
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