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- W2415432673 abstract "The two title compounds are isomers of C 6 H 3 ClN 2 containing a pyridine ring, a nitrile group, and a chloro substituent. The molecules of each compound pack together in the solid state with offset face-to-face π-stacking, and intermolecular C—H...N nitrile and C—H...N pyridine interactions. 4-Chloropyridine-2-carbonitrile, (I), exhibits pairwise centrosymmetric head-to-head C—H...N nitrile and C—H...N pyridine interactions, forming one-dimensional chains, which are π-stacked in an offset face-to-face fashion. The intermolecular packing of the isomeric 6-chloropyridine-2-carbonitrile, (II), which differs only in the position of the chloro substituent on the pyridine ring, exhibits head-to-tail C—H...N nitrile and C—H...N pyridine interactions, forming two-dimensional sheets which are π-stacked in an offset face-to-face fashion. In contrast to (I), the offset face-to-face π-stacking in (II) is formed between molecules with alternating orientations of the chloro and nitrile substituents." @default.
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- W2415432673 date "2015-06-27" @default.
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- W2415432673 title "Crystal structures of 4-chloropyridine-2-carbonitrile and 6-chloropyridine-2-carbonitrile exhibit different intermolecular π-stacking, C—H...N<sub>nitrile</sub>and C—H...N<sub>pyridine</sub>interactions" @default.
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- W2415432673 doi "https://doi.org/10.1107/s2056989015011767" @default.
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