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- W2415665710 abstract "In the coordination chemistry of palladium, dimers bridged via halides are a common motif. Higher oligomers, however, are still rare. We report the structure of an alternating eight-membered [Pd 4 Br 4 ] 4− ring framed by cycloheptatrienide ligands, which was obtained by cocrystallization of dimers and tetramers of the complex salt bromido{η 3 -[3-(2,6-diisopropylphenyl)imidazolium-1-yl]cycloheptatrienido}palladium(II) tetrafluoroborate, namely bis[di-μ-bromido-bis({η 3 -[3-(2,6-diisopropylphenyl)imidazolium-1-yl]cycloheptatrienido}palladium(II))] cyclo -tetra-μ-bromido-tetrakis({η 3 -[3-(2,6-diisopropylphenyl)imidazolium-1-yl]cycloheptatrienido}palladium(II)) octakis(tetrafluoroborate) dichloromethane octasolvate, [Pd 4 Br 4 (C 22 H 26 N 2 ) 4 ][Pd 2 Br 2 (C 22 H 26 N 2 ) 2 ] 2 (BF 4 ) 8 ·8CH 2 Cl 2 . These dimers and tetramers form a highly dynamic equilibrium in solution which was studied by low-temperature NMR spectroscopy. In the light of the presented results, tetrameric Pd II species can be assumed to co-exist as a second species in many cases where by current knowledge only a dimeric compound would be expected." @default.
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- W2415665710 date "2016-06-03" @default.
- W2415665710 modified "2023-09-27" @default.
- W2415665710 title "A Pd4Br4macrocycle trapped by cocrystallization from a highly dynamic equilibrium of η3-cycloheptatrienide complexes" @default.
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- W2415665710 doi "https://doi.org/10.1107/s2053229616008275" @default.
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