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- W2415696038 abstract "A selection of new η8-permethylpentalene zirconium and hafnium complexes are reported. The first d-block metal bis(permethylpentalene) sandwich complexes, (Pn*2M ; Pn* = C8Me6 ; M = Zr, Hf) have been synthesized and structurally characterized. The bis-allyl species Pn*M(C3H5)2 (M = Zr, Hf) have been synthesized; these complexes are fluxional in solution and react with CO2 to give the double-insertion product Pn*M(κ2-O2CCH2CHCH2)2 (M = Zr, Hf). We also report monometallic, bimetallic, and polymeric σ-bonded alkyl derivatives such as (Pn*Zr)2(μ-CH2)(μ-Me)2, [Pn*Hf(CH2Ph)3][Li(1,4-dioxane)4], and [Pn*ZrPh(μ-Ph)2Li(μ-1,4-dioxane)]n." @default.
- W2415696038 created "2016-06-24" @default.
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- W2415696038 date "2016-06-09" @default.
- W2415696038 modified "2023-10-17" @default.
- W2415696038 title "Zirconium and Hafnium Permethylpentalene Compounds" @default.
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- W2415696038 doi "https://doi.org/10.1021/acs.organomet.6b00301" @default.
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