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- W2416174969 abstract "3,3,3-Trifluoropropynyllithium, in situ generated by treatment of 2-bromo-3,3,3-trifluoro-1-propene 1 with 2.0 equiv. of LDA at -78 degrees C, was trapped with D-glyceraldimine 2 to give trifluoromethylated propargylic amine 4 in 55% yield. Starting from the key intermediate 4, Boc-protected (R)-5,5,5-trifluoronorvaline and (S)-5,5,5-trifluoronorvaline were concisely synthesized over three steps in 62% and 63% yield, respectively. (C) 2007 Published by Elsevier B.V." @default.
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- W2416174969 date "2007-01-01" @default.
- W2416174969 modified "2023-09-23" @default.
- W2416174969 title "Nucleophilic addition of 3,3,3-trifluoropropynyllithium to D-glyceraldimine: Concise synthesis of both enantiomers of 5,5,5-trifluoronorvaline" @default.
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