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- W2416232964 endingPage "8757" @default.
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- W2416232964 abstract "A Cu-catalyzed three-component cross-coupling reaction of terminal alkyne, α-diazo ester, and alkyl halide has been developed. This transformation involves sequent migratory insertion of copper-carbene and nucleophilic substitution, in which a C(sp)-C(sp(3)) bond and a C(sp(3))-C(sp(3)) bond are formed successively on a carbenic center. Michael addition acceptors can also be employed instead of alkyl halides that enable Michael addition to be an alternative way to build C(sp(3))-C(sp(3)) bond. This transformation represents a highly efficient method for the construction of all-carbon quaternary centers." @default.
- W2416232964 created "2016-06-24" @default.
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- W2416232964 date "2015-08-26" @default.
- W2416232964 modified "2023-10-07" @default.
- W2416232964 title "Construction of All-Carbon Quaternary Centers through Cu-Catalyzed Sequential Carbene Migratory Insertion and Nucleophilic Substitution/Michael Addition" @default.
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- W2416232964 doi "https://doi.org/10.1021/acs.joc.5b01592" @default.
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