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- W2416615456 abstract "The syntheses and crystal structures of 0.25-aqua(benzene-1,4-dicarboxylato-κ 2 O , O ′)bis(sparfloxacin-κ 2 O , O ′)manganese(II) dihydrate, [Mn(C 8 H 4 O 4 )(C 19 H 22 F 2 N 4 O 3 ) 2 (H 2 O) 0.25 ]·2H 2 O or [Mn(bdc)(Hspar) 2 (H 2 O) 0.25 ]·2H 2 O, (I), and bis(sparfloxacin-κ 2 O , O ′)copper(II) benzene-1,4-dicarboxylate dihydrate, [Cu(C 19 H 22 F 2 N 4 O 3 ) 2 ](C 8 H 4 O 4 )·2H 2 O or [Cu(Hspar) 2 ](bdc)·2H 2 O, (II), are reported (Hspar = sparfloxacin and bdc = benzene-1,4-dicarboxylate). The Mn 2+ ion in (I) is coordinated by two O , O ′-bidentate Hspar neutral molecules (which exist as zwitterions) and an O , O ′-bidentate bdc dianion to generate a distorted MnO 6 trigonal prism. A very long bond [2.580 (12) Å] from the Mn 2+ ion to a 0.25-occupied water molecule projects through a square face of the prism. In (II), the Cu 2+ ion lies on a crystallographic inversion centre and a CuO 4 square-planar geometry arises from its coordination by two O , O ′-bidentate Hspar molecules. The bdc dianion acts as a counter-ion to the cationic complex and does not bond to the metal ion. The Hspar ligands in both (I) and (II) feature intramolecular N—H...O hydrogen bonds, which close S (6) rings. In the crystals of both (I) and (II), the components are linked by N—H...O, O—H...O and C—H...O hydrogen bonds, generating three-dimensional networks." @default.
- W2416615456 created "2016-06-24" @default.
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- W2416615456 date "2016-01-01" @default.
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- W2416615456 title "Crystal structures of [Mn(bdc)(Hspar)<sub>2</sub>(H<sub>2</sub>O)<sub>0.25</sub>]·2H<sub>2</sub>O containing MnO<sub>6+1</sub>capped trigonal prisms and [Cu(Hspar)<sub>2</sub>](bdc)·2H<sub>2</sub>O containing CuO<sub>4</sub>squares (Hspar = sparfloxacin and bdc = benzene-1,4-dicarboxylate)" @default.
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- W2416615456 doi "https://doi.org/10.1107/s205698901502424x" @default.
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