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- W2418389840 endingPage "10032" @default.
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- W2418389840 abstract "Phosphinylidene compounds R(1)R(2)P(O)H are important functionalities in organophosphorus chemistry and display prototropic tautomerism. Quantifying the tautomerization rate is paramount to understanding these compounds' tautomerization behavior, which may impact their reactivities in various reactions. We report a combined theoretical and experimental study of the initial tautomerization rate of a range of phosphinylidene compounds. Initial tautomerization rates are found to decrease in the order H3PO2 > Ph2P(O)H > (PhO)2P(O)H > PhP(O) (OAlk)H > AlkP(O)(OAlk)H ≈ (AlkO)2P(O)H, where Alk denotes an alkyl substituent. The combination of computational investigations with experimental validation establishes a quantitative measure for the reactivity of various phosphorus compounds, as well as an accurate predictive tool." @default.
- W2418389840 created "2016-06-24" @default.
- W2418389840 creator A5014557092 @default.
- W2418389840 creator A5023929087 @default.
- W2418389840 creator A5083307625 @default.
- W2418389840 creator A5089825945 @default.
- W2418389840 date "2015-09-29" @default.
- W2418389840 modified "2023-10-03" @default.
- W2418389840 title "P(═O)H to P–OH Tautomerism: A Theoretical and Experimental Study" @default.
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- W2418389840 doi "https://doi.org/10.1021/acs.joc.5b01618" @default.
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- W2418389840 hasPublicationYear "2015" @default.
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