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- W2418465282 abstract "A new enantiodivergent synthesis of P-chirogenic 1,2-diphosphinobenzenes (DP*B) bearing the chirality on one or both phosphorus centers is reported using aryne chemistry. The principle is based on successive reactions of 1,2-dibromobenzene with sec-phosphide boranes, then DABCO to remove the borane, and finally with chlorophosphines or P(III)-chirogenic phosphinites. The efficiency of this synthesis was demonstrated by the stereoselective preparation of (S,S)-1,2-bis(o-anisylphenylphosphino)benzene. A comparison of DIPAMP and homochiral DP*B ligands in asymmetric Rh- or Pd-catalyzed reactions was reported." @default.
- W2418465282 created "2016-06-24" @default.
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- W2418465282 date "2016-05-31" @default.
- W2418465282 modified "2023-10-16" @default.
- W2418465282 title "Designing P-Chirogenic 1,2-Diphosphinobenzenes at Both P-Centers Using P(III)-Phosphinites" @default.
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- W2418465282 doi "https://doi.org/10.1021/acs.orglett.6b01275" @default.
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