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• W2420435678 abstract "Dynamic kinetic resolutions of α-stereogenic-β-formyl amides in asymmetric 2-aza-Cope rearrangements are described. Chiral phosphoric acids catalyze this rare example of a non-hydrogenative DKR of a β-oxo acid derivative. The [3,3]-rearrangement occurs with high diastereo- and enantiocontrol, forming β-imino amides that can be deprotected to the primary β-amino amide or reduced to the corresponding diamine." @default.
• W2420435678 created "2016-06-24" @default.
• W2420435678 creator A5044813315 @default.
• W2420435678 creator A5057695381 @default.
• W2420435678 date "2015-11-12" @default.
• W2420435678 modified "2023-10-07" @default.
• W2420435678 title "Asymmetric Synthesis of β-Amino Amides by Catalytic Enantioconvergent 2-Aza-Cope Rearrangement" @default.
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• W2420435678 doi "https://doi.org/10.1021/jacs.5b09593" @default.
• W2420435678 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4661081" @default.
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