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- W242094889 abstract "The extremal geometries which characterize non-cubo-symmetric molecules in degenerate electronic states are particularized, and their relative stabilities discussed. It is shown how, although statically stable, a given geometrical orientation may become dynamically unstable. The nuclear motions (for zero spin-orbit forces) by which such dynamic destabilizations occur will be described in both the physical and (mathematically) abstract spaces. Specific examples from amongst the more common molecular conformations will be studied. Special attention will be given to the trigonal (e.g. pyramidal) and tetragonal (e.g. square planar) spatial arrangements. Some recent experimental confirmations of the theory will be considered and analyzed, and a plea for future caution in experimental rationalizations will be entered." @default.
- W242094889 created "2016-06-24" @default.
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- W242094889 date "1964-01-01" @default.
- W242094889 modified "2023-09-23" @default.
- W242094889 title "CONFORMATION INSTABILITY OF NON-CUBO-SYMMETRIC INORGANIC COMPOUNDS IN DEGENERATE ELECTRONIC STATES" @default.
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- W242094889 doi "https://doi.org/10.1016/b978-1-4832-2841-9.50014-3" @default.
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