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- W2421403944 abstract "Two dinuclear iron(II) complexes [Fe2(μ-L)2]X4*4DMF (X = BF4– (1·4DMF) and ClO4– (2·4DMF)) with a 1,3,4-thiadiazole bridging ligand have been synthesized and show a very distinct solvent-depending SCO behavior. The complexes represent new solvatomorphs of the first dinuclear iron(II) complexes with the ligand L (2,5-bis[(2-pyridylmethyl)amino]methyl-1,3,4-thiadiazole). The incorporated lattice DMF molecules directly affect the spin state of these complexes. This behavior reveals a structural insight into the role of the solvent molecules on the spin transition." @default.
- W2421403944 created "2016-06-24" @default.
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- W2421403944 creator A5051926683 @default.
- W2421403944 creator A5062953691 @default.
- W2421403944 date "2016-06-13" @default.
- W2421403944 modified "2023-10-03" @default.
- W2421403944 title "Solvent-dependent SCO Behavior of Dinuclear Iron(II) Complexes with a 1,3,4-Thiadiazole Bridging Ligand" @default.
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- W2421403944 doi "https://doi.org/10.1021/acs.inorgchem.6b00163" @default.
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