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- W2423849315 abstract "Abstract The influence of the carbohydrate moiety on the chromatographic behaviour of heart glycosides and their genins is demonstrated for 15 sugars using ΔRM values. On the basis of conformation theory, intramolecular hydrogen bonding, steric hindrance, and dipole interactions, an explanation for the differences between the polarity of these carbohydrates is presented. ΔRM values arising from acetylation or configurational changes are discussed. Starting from the chromatographic data of about 180 cardiac glycosides and genins examples for the calculation of RM values are given. The application of MARTIN'S theory to problems of structure elucidation is shown with Erycanoside, Syriobioside, Syrioside, and Rhodexin C, the chromatographic behaviour of which does not correspond to their presumed chemical structure. For Erycanoside and Rhodexin C a revised structure is suggested." @default.
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- W2423849315 date "1968-01-01" @default.
- W2423849315 modified "2023-09-25" @default.
- W2423849315 title "Über die beziehungen zwischen chemischer struktur und chromatographischem verhalten bei herzglykosiden" @default.
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- W2423849315 doi "https://doi.org/10.1016/s0021-9673(01)80477-5" @default.
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