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• W2424305305 abstract "Abstract S r 2 I r O 4 exhibits a novel insulating state assisted by spin-orbit interactions. A series of polycrystalline samples of S r 2 − x I r O 4 have been synthesized. It is found that deep Sr-vacancies of S r 2 − x I r O 4 greatly reduce the rotation of I r O 6 octahedral, and more importantly, a significant structural change occurs around x = 0.48 in both the lattice constants and the I r − O 2 bond length. An insulator-metal transition (IMT) appears and a non-Fermi-liquid metallic electronic state has been proved at x > 0.48 in S r 2 − x I r O 4 . Furthermore, a sudden drop emerges of the localization temperature T 0 and the antiferromagnetic (AFM) transition temperature T N in S r 1.5 I r O 4 , together with the Curie-Weiss temperature reversing its sign. These abrupt changes are closely related with the reduction of the rotation crystal structure." @default.
• W2424305305 created "2016-06-24" @default.
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• W2424305305 date "2016-12-01" @default.
• W2424305305 modified "2023-09-28" @default.
• W2424305305 title "Insulator-metal transition in deep Sr-vacant spin-orbit Mott insulator S2IrO4" @default.
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• W2424305305 doi "https://doi.org/10.1016/j.jallcom.2016.06.110" @default.
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