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• W2425677913 abstract "Abstract In this study, we introduce AlF 3 -coated LiMn 2 O 4 cathodes, which are cost-effective and environmentally benign, for use in the aqueous rechargeable lithium-ion battery. The homogeneous AlF 3 coating on the LiMn 2 O 4 powder is synthesized by a simple chemical deposition method. The thickness of the coating is controlled by varying the quantity of AlF 3 used, in order to optimize the balance between polarization and surface stabilization. The optimized LiMn 2 O 4 , having 2 wt% coating of AlF 3 , exhibits a long cycle life having a capacity retention of 90% after 100 cycles, and a highly improved rate capability, when compared with the pristine LiMn 2 O 4 material, in 1 M Li 2 SO 4 aqueous electrolyte solution. The systematic surface analyses, comprising scanning electron microscopy, X-ray photoelectron spectroscopy, and electrochemical analyses, indicate that the AlF 3 coating on the LiMn 2 O 4 surface successfully reduces the surface deterioration of LiMn 2 O 4 caused by side reactions between the electrolyte solution and the active material." @default.
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• W2425677913 date "2016-09-01" @default.
• W2425677913 modified "2023-10-12" @default.
• W2425677913 title "AlF3-coated LiMn2O4 as cathode material for aqueous rechargeable lithium battery with improved cycling stability" @default.
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• W2425677913 doi "https://doi.org/10.1016/j.jpowsour.2016.06.049" @default.
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