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• W2426077495 abstract "A counterintuitive approach to electrophilic aromatic substitution with silicon electrophiles is disclosed. A strong Brønsted acid that would usually promote the reverse reaction, i.e., protodesilylation, was found to initiate the C-H silylation of electron-rich (hetero)arenes with hydrosilanes. Protonation of the hydrosilane followed by liberation of dihydrogen is key to success, fulfilling two purposes: to generate the stabilized silylium ion and to remove the proton released from the Wheland intermediate." @default.
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• W2426077495 date "2016-06-20" @default.
• W2426077495 modified "2023-10-09" @default.
• W2426077495 title "Brønsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel–Crafts C–H Silylation" @default.
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• W2426077495 doi "https://doi.org/10.1021/jacs.6b04878" @default.
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