FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2426490911> ?p ?o ?g. }

• W2426490911 endingPage "9238" @default.
• W2426490911 startingPage "9234" @default.
• W2426490911 abstract "Abstract Although the major isomers of M@C 82 (namely M@ C 2 v (9)‐C 82 , where M is a trivalent rare‐earth metal) have been intensively investigated, the lability of the minor isomers has meant that they have been little studied. Herein, the first isolation and crystallographic characterization of the minor Y@C 82 isomer, unambiguously assigned as Y@ C s (6)‐C 82 by cocrystallization with Ni(octaethylporphyrin), is reported. Unexpectedly, a regioselective dimerization is observed in the crystalline state of Y@ C s (6)‐C 82 . In sharp contrast, no dimerization occurs for the major isomer Y@ C 2 v (9)‐C 82 under the same conditions, indicating a cage‐symmetry‐induced dimerization process. Further experimental and theoretical results disclose that the regioselective dimer formation is a consequence of the localization of high spin density on a special cage‐carbon atom of Y@ C s (6)‐C 82 which is caused by the steady displacement of the Y atom inside the C s (6)‐C 82 cage." @default.
• W2426490911 created "2016-06-24" @default.
• W2426490911 creator A5020699341 @default.
• W2426490911 creator A5055015942 @default.
• W2426490911 creator A5055244809 @default.
• W2426490911 creator A5059546616 @default.
• W2426490911 creator A5076963678 @default.
• W2426490911 creator A5078853797 @default.
• W2426490911 date "2016-06-15" @default.
• W2426490911 modified "2023-10-14" @default.
• W2426490911 title "Isolation and Crystallographic Characterization of the Labile Isomer of Y@C ₈₂ Cocrystallized with Ni(OEP): Unprecedented Dimerization of Pristine Metallofullerenes" @default.
• W2426490911 cites W1659675654 @default.
• W2426490911 cites W1979271488 @default.
• W2426490911 cites W1989065761 @default.
• W2426490911 cites W2009732751 @default.
• W2426490911 cites W2024809943 @default.
• W2426490911 cites W2038619825 @default.
• W2426490911 cites W2046187422 @default.
• W2426490911 cites W2048705692 @default.
• W2426490911 cites W2057711827 @default.
• W2426490911 cites W2057937320 @default.
• W2426490911 cites W2067368043 @default.
• W2426490911 cites W2073722828 @default.
• W2426490911 cites W2073964298 @default.
• W2426490911 cites W2081736895 @default.
• W2426490911 cites W2082881735 @default.
• W2426490911 cites W2085330746 @default.
• W2426490911 cites W2090424147 @default.
• W2426490911 cites W2109754100 @default.
• W2426490911 cites W2110087267 @default.
• W2426490911 cites W2114121118 @default.
• W2426490911 cites W2316505668 @default.
• W2426490911 cites W2324064300 @default.
• W2426490911 cites W2329313887 @default.
• W2426490911 cites W2330694417 @default.
• W2426490911 cites W2951270617 @default.
• W2426490911 cites W4211265508 @default.
• W2426490911 cites W4241757207 @default.
• W2426490911 cites W4249091035 @default.
• W2426490911 cites W4249862469 @default.
• W2426490911 doi "https://doi.org/10.1002/anie.201604121" @default.
• W2426490911 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27305624" @default.
• W2426490911 hasPublicationYear "2016" @default.
• W2426490911 type Work @default.
• W2426490911 sameAs 2426490911 @default.
• W2426490911 citedByCount "35" @default.
• W2426490911 countsByYear W24264909112016 @default.
• W2426490911 countsByYear W24264909112017 @default.
• W2426490911 countsByYear W24264909112018 @default.
• W2426490911 countsByYear W24264909112019 @default.
• W2426490911 countsByYear W24264909112020 @default.
• W2426490911 countsByYear W24264909112021 @default.
• W2426490911 countsByYear W24264909112022 @default.
• W2426490911 countsByYear W24264909112023 @default.
• W2426490911 crossrefType "journal-article" @default.
• W2426490911 hasAuthorship W2426490911A5020699341 @default.
• W2426490911 hasAuthorship W2426490911A5055015942 @default.
• W2426490911 hasAuthorship W2426490911A5055244809 @default.
• W2426490911 hasAuthorship W2426490911A5059546616 @default.
• W2426490911 hasAuthorship W2426490911A5076963678 @default.
• W2426490911 hasAuthorship W2426490911A5078853797 @default.
• W2426490911 hasConcept C114614502 @default.
• W2426490911 hasConcept C142724271 @default.
• W2426490911 hasConcept C149635348 @default.
• W2426490911 hasConcept C149997192 @default.
• W2426490911 hasConcept C160272327 @default.
• W2426490911 hasConcept C161790260 @default.
• W2426490911 hasConcept C178790620 @default.
• W2426490911 hasConcept C185592680 @default.
• W2426490911 hasConcept C202235601 @default.
• W2426490911 hasConcept C204787440 @default.
• W2426490911 hasConcept C2776910235 @default.
• W2426490911 hasConcept C2779546866 @default.
• W2426490911 hasConcept C33923547 @default.
• W2426490911 hasConcept C41008148 @default.
• W2426490911 hasConcept C544153396 @default.
• W2426490911 hasConcept C58312451 @default.
• W2426490911 hasConcept C59759590 @default.
• W2426490911 hasConcept C71240020 @default.
• W2426490911 hasConcept C71924100 @default.
• W2426490911 hasConcept C8010536 @default.
• W2426490911 hasConceptScore W2426490911C114614502 @default.
• W2426490911 hasConceptScore W2426490911C142724271 @default.
• W2426490911 hasConceptScore W2426490911C149635348 @default.
• W2426490911 hasConceptScore W2426490911C149997192 @default.
• W2426490911 hasConceptScore W2426490911C160272327 @default.
• W2426490911 hasConceptScore W2426490911C161790260 @default.
• W2426490911 hasConceptScore W2426490911C178790620 @default.
• W2426490911 hasConceptScore W2426490911C185592680 @default.
• W2426490911 hasConceptScore W2426490911C202235601 @default.
• W2426490911 hasConceptScore W2426490911C204787440 @default.
• W2426490911 hasConceptScore W2426490911C2776910235 @default.
• W2426490911 hasConceptScore W2426490911C2779546866 @default.
• W2426490911 hasConceptScore W2426490911C33923547 @default.
• W2426490911 hasConceptScore W2426490911C41008148 @default.
• W2426490911 hasConceptScore W2426490911C544153396 @default.
• W2426490911 hasConceptScore W2426490911C58312451 @default.
• W2426490911 hasConceptScore W2426490911C59759590 @default.

• next